rare earth preconcentration

Preconcentration of Rare Earth Elements Using Amberlite ...

2014-4-27 · A new solid phase extraction method was developed for the preconcentration and determination of rare earth elements (REEs) (Nd, Sm, Eu, Gd, Tb, Dy, Ho, Yb, Lu, Ce) in water samples. The method is based on the sorption of REE ions onto the 2,6-pyridinedicarboxaldehyde-functionalized Amberlite XAD-4 resin at pH 7.0, followed by the elution with 2 mL of 1.0 mol L−1 HNO3 solution and ...

Preconcentration and Purification of Rare Earth Elements ...

1994-5-15 · On-line preconcentration of some rare earth elements in water samples using C18-cartridge modified with l-(2-pyridylazo) 2-naphtol (PAN) prior to simultaneous determination by inductively coupled plasma optical emission spectrometry (ICP–OES). Analytica Chimica Acta 2005, 540 (2) , 325-332.

Separation/Preconcentration Techniques for Rare Earth ...

2016-10-1 · The main aim of this chapter exactly characterizes the contribution. The analytical chemistry of the rare earth elements (REEs) very often is highly complicated and the determination of a specific element is impossible without a sample pre-concentration. Sample preparation can be carried out either by separation of the REEs from the matrix or by concentrating the REEs. The separation of REEs ...

Preconcentration of Rare Earth Elements in Seawater with ...

1998-8-13 · A new ion-exchange chelating fiber with aminophosphonic and dithiocarbamate groups based on polyacrylonitrile was developed for the preconcentration of rare earth elements (REEs) in seawater prior to their determination by inductively coupled plasma mass spectrometry. REEs can be easily separated from the high-saline matrix using the fiber. The optimum experimental parameters

Online preconcentration ICP‐MS analysis of rare earth ...

2012-1-31 · 1. Introduction [2] The rare earth elements (REEs) are chemically similar but their ionic radii decrease with increasing atomic number resulting in systematic differences in their speciation in seawater [e.g., Cantrell and Byrne, 1987; Elderfield, 1988; Quinn et al., 2006].This and the special case of cerium III oxidation to the insoluble cerium IV state combine to make the REEs useful tracers ...

Matrix separation and preconcentration of rare earth ...

2011-10-17 · The determination of rare earth elements in seawater is a challenge due to high salt content of seawater and extremely low concentrations of rare earth elements. Therefore separation of matrix and preconcentration of rare earth elements is necessary for their detection by inductively coupled plasma mass spectrometer.

Preconcentration of Iron, Rare Earth, and Fluorite from ...

2020-9-15 · Rare earth elements (REE), comprising of 17 metal elements (15 lanthanides as well as scandium and yttrium) [], are strategic metals used in a wide range of

Pre-concentration of fluorite from a rare earth element ...

2021-6-12 · 1. Introduction. The main challenge for rare earth element (REE) extraction from primary deposits is the low concentration of REE-bearing minerals present in a variety of gangue minerals, including silicates, carbonates, fluorites, and/or phosphates (Vijayan et al., 1989).Among the residues generated during the pre-concentration of rare earth minerals from certain carbonatite deposits (e.g ...

Online preconcentration ICP-MS analysis of rare earth ...

Online preconcentration ICP-MS analysis of rare earth elements in seawater Ed C. Hathorne Helmholtz Centre for Ocean Research Kiel (GEOMAR), D-24148 Kiel, Germany ([email protected]) Brian Haley College of Ocean and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA Torben Stichel

Biosorption-a green method for the preconcentration of ...

2019-1-15 · An EDTA-β-cyclodextrin material for the adsorption of rare earth elements and its application in preconcentration of rare earth elements in seawater J. Colloid Interface Sci. , 465 ( 2016 ) , pp. 215 - 224 , 10.1016/j.jcis.2015.11.069

Preconcentration of rare earth elements on activated ...

Preconcentration of rare earth elements on activated carbon and its application to groundwater and sea-water analysis D. S. R. Murty and G. Chakrapani, J. Anal. At. Spectrom., 1996, 11, 815 DOI: 10.1039/JA9961100815

Preconcentration and Purification of Rare Earth Elements ...

1994-5-15 · On-line preconcentration of some rare earth elements in water samples using C18-cartridge modified with l-(2-pyridylazo) 2-naphtol (PAN) prior to simultaneous determination by inductively coupled plasma optical emission spectrometry (ICP–OES). Analytica Chimica Acta 2005, 540 (2) , 325-332.

Preconcentration of Rare Earth Elements Using Amberlite ...

2014-4-27 · A new solid phase extraction method was developed for the preconcentration and determination of rare earth elements (REEs) (Nd, Sm, Eu, Gd, Tb, Dy, Ho, Yb, Lu, Ce) in water samples. The method is based on the sorption of REE ions onto the 2,6-pyridinedicarboxaldehyde-functionalized Amberlite XAD-4 resin at pH 7.0, followed by the elution with 2 mL of 1.0 mol L−1 HNO3 solution and ...

Separation/Preconcentration Techniques for Rare Earth ...

The main aim of this chapter exactly characterizes the contribution. The analytical chemistry of the rare earth elements (REEs) very often is highly complicated and the determination of a specific element is impossible without a sample pre-concentration. Sample preparation can be carried out either by separation of the REEs from the matrix or by concentrating the REEs. The separation of REEs ...

Preconcentration of Rare Earth Elements in Seawater with ...

1998-8-13 · A new ion-exchange chelating fiber with aminophosphonic and dithiocarbamate groups based on polyacrylonitrile was developed for the preconcentration of rare earth elements (REEs) in seawater prior to their determination by inductively coupled plasma mass spectrometry. REEs can be easily separated from the high-saline matrix using the fiber. The optimum experimental parameters

Online preconcentration ICP-MS analysis of rare earth ...

Online preconcentration ICP-MS analysis of rare earth elements in seawater Ed C. Hathorne Helmholtz Centre for Ocean Research Kiel (GEOMAR), D-24148 Kiel, Germany ([email protected]) Brian Haley College of Ocean and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA Torben Stichel

A Preconcentration/Matrix Reduction Method for the ...

2003-6-3 · A simple method of simultaneous preconcentration and matrix reduction was developed for the analysis of rare earth elements (REEs) in seawater and groundwater by ID ICPMS. The method utilizes partitioning of the REEs with solid hydroxides to separate them from soluble matrix species (e.g., Ba2+, NOM, seawater salts). Acidified samples were spiked and equilibrated with an enriched isotope ...

Preconcentration and elimination of matrix effects in XRF ...

Trace rare earth elements (REE) can be enriched by collecting them on a filter after they have formed their complexes with 2,2′-(1,8-dihydroxy-3,6-disulfonaphthylene-2,7-bisazo)bisbenzenearsonic acid (Arsenazo III) through a process called chemofiltration. The filter, which constitutes a thin film, is passed

(PDF) Recovery of rare earths from a bastnaesite ...

The system for on-line microcolumn sorption preconcentration and inductively coupled plasma atomic emission spectrometry determination of 14 rare earth elements (REEs) is described ...

Determination of trace rare earth elements by inductively ...

2006-12-28 · P Liang X G Chen (2005) ArticleTitle Preconcentration of rare earth elements with silica gel loaded with 1-phenyl-3-methyl-4-benzoylpyrazol-5-one prior to their determination by ICP-AES Anal Sci 21 1185 Occurrence Handle 10.2116/analsci.21.1185 Occurrence Handle 1:CAS:528:DC%2BD2MXhtFGmtbrE

Preconcentration of rare earth elements on activated ...

Preconcentration of rare earth elements on activated carbon and its application to groundwater and sea-water analysis D. S. R. Murty and G. Chakrapani, J. Anal. At. Spectrom., 1996, 11, 815 DOI: 10.1039/JA9961100815

Preconcentration and Purification of Rare Earth Elements ...

1994-5-15 · On-line preconcentration of some rare earth elements in water samples using C18-cartridge modified with l-(2-pyridylazo) 2-naphtol (PAN) prior to simultaneous determination by inductively coupled plasma optical emission spectrometry (ICP–OES). Analytica Chimica Acta 2005, 540 (2) , 325-332.

Preconcentration of Rare Earth Elements in Seawater with ...

1998-8-13 · A new ion-exchange chelating fiber with aminophosphonic and dithiocarbamate groups based on polyacrylonitrile was developed for the preconcentration of rare earth elements (REEs) in seawater prior to their determination by inductively coupled plasma mass spectrometry. REEs can be easily separated from the high-saline matrix using the fiber. The optimum experimental parameters

Online preconcentration ICP-MS analysis of rare earth ...

Online preconcentration ICP-MS analysis of rare earth elements in seawater Ed C. Hathorne Helmholtz Centre for Ocean Research Kiel (GEOMAR), D-24148 Kiel, Germany ([email protected]) Brian Haley College of Ocean and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA Torben Stichel

Online preconcentration ICP-MS analysis of rare earth ...

A preconcentration/matrix reduction method for the analysis of rare earth elements in seawater and groundwaters by isotope dilution ICPMS, Alibo (2003), Importance of vertical geochemical processes in controlling the oceanic profiles of dissolved rare earth elements

(PDF) Determination of rare earth elements in small

Determination of rare earth elements in small-volume seawater by off-line preconcentration system and inductively coupled plasma mass spectrometry September 2011 Authors:

Preconcentration and elimination of matrix effects in XRF ...

Trace rare earth elements (REE) can be enriched by collecting them on a filter after they have formed their complexes with 2,2′-(1,8-dihydroxy-3,6-disulfonaphthylene-2,7-bisazo)bisbenzenearsonic acid (Arsenazo III) through a process called chemofiltration. The filter, which constitutes a thin film, is passed

Determination of trace rare earth elements by inductively ...

2006-12-28 · P Liang X G Chen (2005) ArticleTitle Preconcentration of rare earth elements with silica gel loaded with 1-phenyl-3-methyl-4-benzoylpyrazol-5-one prior to their determination by ICP-AES Anal Sci 21 1185 Occurrence Handle 10.2116/analsci.21.1185 Occurrence Handle 1:CAS:528:DC%2BD2MXhtFGmtbrE

ICP-AES determination of trace rare earth elements in ...

A novel method of online microcolumn separation and preconcentration coupled to inductively coupled plasma atomic emission spectrometry (ICP-AES) with the use of acetylacetone-modified silica gel as packing material was developed for the determination of trace rare earth elements (REEs) in environmental and food samples.

1 James Hedrick, Rare Earths, from Mineral Commodity ...

2016-3-27 · The rare earth elements are comprised of scandium, yttrium, and 15 lanthanide elements, of which, cerium, lanthanum, and neodymium are the most abundant. While rare earth elements are found in several minerals, almost all production comes from less than 10 minerals, primarily monazite and bastnasite. Since the scandium industry is, for the